Efficient Lone-Pair-Driven Luminescence: Structure–Property Relationships in Emissive 5s2 Metal Halides
نویسندگان
چکیده
منابع مشابه
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The chemistry of post transition metals is dominated by the group oxidation state N and a lower N-2 oxidation state, which is associated with occupation of a metal s(2) lone pair, as found in compounds of Tl(I), Pb(II) and Bi(III). The preference of these cations for non-centrosymmetric coordination environments has previously been rationalised in terms of direct hybridisation of metal s and p ...
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ژورنال
عنوان ژورنال: ACS Materials Letters
سال: 2020
ISSN: 2639-4979,2639-4979
DOI: 10.1021/acsmaterialslett.0c00211